master's thesis
Synthesis of Macrocyclic Schiff Bases from Diketones and Diamines

Hrvoje Babić (2014)
Metadata
TitleSinteza makrocikličkih Schiffovih baza iz diketona i diamina
AuthorHrvoje Babić
Mentor(s)Berislav Marković (thesis advisor)
Tomislav Balić (thesis advisor)
Abstract
Makrocikli su molekule cikličke strukture od najmanje devet atoma u prstenu. Makrocikli nalaze primjenu u širokom području istraživanja. Makrocikličke Schiffove baze čine dio makrocikličke kemije koji je vrlo popularan zbog njihove jednostavne primjene. U ovome radu opisan je pokušaj dobivanja novih makrocikličkih Schiffovih baza iz diketona i diamina. Pomoću templatne sinteze dobivene su Schiffove baze iz komercijalno dostupnih reaktanata. Dobiveni su i polioksa makrocikli iz priređenih diketona i dialdehida trivijalnog naziva Chalcon-i. Svi dobiveni produkti karakterizirani su FTIR i TG/DSC metodom. Rad također sadržava i metodički dio u kojem je opisana priprema za nastavni sat na temu "Aldehidi i ketoni" za srednju školu, uključujući i radne listiće za pripadajuće pokuse.
KeywordsFTIR macrocycle Schiff base TG/DSC
Parallel title (English)Synthesis of Macrocyclic Schiff Bases from Diketones and Diamines
Committee MembersIvan Vicković (committee chairperson)
Berislav Marković (committee member)
Dajana Gašo-Sokač (committee member)
Tomislav Balić (committee member)
GranterSveučilište Josipa Jurja Strossmayera u Osijeku
Odjel za kemiju
PlaceOsijek
StateCroatia
Scientific field, discipline, subdisciplineNATURAL SCIENCES
Chemistry
Study programme typeuniversity
Study levelgraduate
Study programmeChemistry
Academic title abbreviationmag.educ.chem.
Genremaster's thesis
Language Croatian
Defense date2014-11-13
Parallel abstract (English)
Macrocycles are circular shape molecules consisting of at least nine atoms in a ring. They can be applied in a wide area of research. Macrocyclic Schiff bases are a very popular part of macrocyclic chemistry since they can be easily applied and their synthesis is rather simple due to affordable prices of reagents. This paper describes an attempt of synthesis of novel macrocyclic Schiff bases from diketones and diamines. Using template synthesis, Schiff bases were obtained from commercialy available reagents. Polyoxa macrocycles, trivialy named chalcones, were also obtained from prepared diketones and dialdehydes. Obtained products were characterised with FTIR and TGA-DSC methods of analysis. In the teaching part of the paper a preparation lecture on aldehydes and ketones for the high school chemistry class is proposed. The lecture also includes relevant experiments and handouts.
Parallel keywords (Croatian)FTIR makrocikli Schiffove baze TG/DSC
Resource typetext
Access conditionOpen access
Terms of usehttp://rightsstatements.org/vocab/InC/1.0/
URN:NBNhttps://urn.nsk.hr/urn:nbn:hr:182:772139
CommitterSanda Hasenay