undergraduate thesis
Study of the Oxidation Properties of a Copper Schiff Base Complex by Difeferential Pulse Voltametry

Vedrana Sesar (2015)
Josip Juraj Strossmayer University of Osijek
Department of Chemistry
Department of General, Inorganic and Physical Chemistry and Methodology of Chemistry
Metadata
TitleIspitivanje oksidacijskih svojstava kompleksa bakra sa Schiffovom bazom upotrebom diferencijalne pulsne voltametrije
AuthorVedrana Sesar
Mentor(s)Martina Medvidović-Kosanović (thesis advisor)
Anamarija Šter (thesis advisor)
Abstract
U ovom radu opisana je uporaba diferencijalne pulsne voltametrije u svrhu ispitivanja oksidacijskih svojstava kompleksa bakra sa Schiffovom bazom (1E)-1-N-{[4-(4-{[(E)-N- (2-aminofenil) karboksiimidoil] fenoksi} butoksi) fenil] metiliden} benzen-1,2-diaminom, S36. Snimanjem diferencijalnih pulsnih voltamograma pratila se oksidacija ovoga kompleksa. Dobiveni diferencijalni pulsni voltamogrami snimljeni na elektrodi od staklastog ugljika pokazali su da se bakar u kompleksu oksidira iz Cu+ u Cu2+ . Također se pratio utjecaj promjene koncentracije otopine kompleksa na struju i potencijal oksidacijskog strujnog vrha. Dobiveni voltamogrami pokazuju da struja i potencijal oksidacijskog strujnog vrha rastu s porastom koncentracije.
Keywordsdifferential pulse voltammetry Schiff base metal complex oxidation
Parallel title (English)Study of the Oxidation Properties of a Copper Schiff Base Complex by Difeferential Pulse Voltametry
GranterJosip Juraj Strossmayer University of Osijek
Department of Chemistry
Lower level organizational unitsDepartment of General, Inorganic and Physical Chemistry and Methodology of Chemistry
PlaceOsijek
StateCroatia
Scientific field, discipline, subdisciplineNATURAL SCIENCES
Chemistry
Study programme typeuniversity
Study levelundergraduate
Study programmeChemistry
Academic title abbreviationuniv. bacc. chem.
Genreundergraduate thesis
Language Croatian
Defense date2015-08-07
Parallel abstract (English)
In this work, an application of differential pulse voltammetry on testing of oxidation properties of the copper complex with Schiff base (1E)-1-N-{[4-(4-{[(E)-N-(2- aminophenyl) carboxyimidoyl] phenoxy} butoxy) phenyl] methilidene} benzene -1,2- diamine, S36 is described. By recording defferential pulse voltammograms, oxidation of this complex was followed. Gained results of the differential pulse voltammograms, recorded on glassy carbon electrode, showed that cooper in the complex oxidated from Cu+ to Cu2+. The influence of concentration change of solution of the complex on oxidation peak current and potential, was also monitored. Obtained voltammograms showed that oxidation peak current and potential increased with an increase of concentration.
Parallel keywords (Croatian)diferencijalna pulsna voltametrija metalni kompleks Schiffove baze oksidacija
Resource typetext
Access conditionOpen access
Terms of usehttp://rightsstatements.org/vocab/InC/1.0/
URN:NBNhttps://urn.nsk.hr/urn:nbn:hr:182:434487
CommitterSanda Hasenay